Dynamic 2D Manganese(II) Isonicotinate Framework with Reversible Crystal-To-Amorphous Transformation and Selective Guest Adsorption

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dc.contributor.utaustinauthorTodd, Alexander D.en_US
dc.contributor.utaustinauthorBielawski, Christopher W.en_US
dc.creatorMatoga, Dariuszen_US
dc.creatorGil, Barbaraen_US
dc.creatorNitek, Wojciechen_US
dc.creatorTodd, Alexander D.en_US
dc.creatorBielawski, Christopher W.en_US
dc.date.accessioned2016-09-23T18:04:42Z
dc.date.available2016-09-23T18:04:42Z
dc.date.issued2014-04en_US
dc.description.abstractA 2D layered microporous isonicotinate-supported manganese(II) metal-organic framework was found to exhibit a reversible crystalto-amorphous transformation upon the removal and uptake of certain guest molecules. Unsaturated metal centers, generated in the dynamic framework upon activation, were found to facilitate the selective adsorption of CO2 versus N-2.en_US
dc.description.departmentChemistryen_US
dc.description.sponsorshipNational Science Centre in Poland 2012/07/B/ST5/00904en_US
dc.description.sponsorshipEuropean Regional Development Fund in the framework of the Polish Innovation Economy Operational Program POIG.02.01.00-12-023/08en_US
dc.description.sponsorshipNational Science Foundation CHE-1266323en_US
dc.identifierdoi:10.15781/T28911S17
dc.identifier.citationMatoga, Dariusz, Barbara Gil, Wojciech Nitek, Alexander D. Todd, and Christopher W. Bielawski. "Dynamic 2D manganese (II) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption." CrystEngComm 16, no. 23 (Apr., 2014): 4959-4962.en_US
dc.identifier.doi10.1039/c4ce00647jen_US
dc.identifier.issn1466-8033en_US
dc.identifier.urihttp://hdl.handle.net/2152/41015
dc.language.isoEnglishen_US
dc.relation.ispartofen_US
dc.relation.ispartofserialCrystengcommen_US
dc.rightsAdministrative deposit of works to Texas ScholarWorks: This works author(s) is or was a University faculty member, student or staff member; this article is already available through open access or the publisher allows a PDF version of the article to be freely posted online. The library makes the deposit as a matter of fair use (for scholarly, educational, and research purposes), and to preserve the work and further secure public access to the works of the University.en_US
dc.rights.restrictionOpenen_US
dc.subjectmetal-organic frameworksen_US
dc.subjecthydrogen storage propertiesen_US
dc.subjectmn2+ coordinationen_US
dc.subjectsitesen_US
dc.subjectmagnetic-propertiesen_US
dc.subjectgas-adsorptionen_US
dc.subjectco2 captureen_US
dc.subjectseparationen_US
dc.subjectstabilityen_US
dc.subjectalcoholsen_US
dc.subjectchannelsen_US
dc.subjectchemistry, multidisciplinaryen_US
dc.subjectcrystallographyen_US
dc.titleDynamic 2D Manganese(II) Isonicotinate Framework with Reversible Crystal-To-Amorphous Transformation and Selective Guest Adsorptionen_US
dc.typeArticleen_US

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