Introduction
Texas ScholarWorks was established to provide open, online access to the products of the University's research and scholarship, to preserve these works for future generations, to promote new models of scholarly communication, and to help deepen community understanding of the value of higher education.
UT Tower and campus image credit: Earl McGehee, CC-BY, https://www.flickr.com/photos/ejmc/7452145850
Recently Added
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Top-Down Strategies for the Structural Elucidation of Intact Gram-Negative Bacterial Endotoxins
(2014-07)Re-modelling of lipopolysaccharides, which are the primary constituent of the outer cell membrane of Gram-negative bacteria, modulates pathogenesis and resistance to microbials. Reported herein is the characterization of ... -
Well Plate Circular Dichroism Reader for the Rapid Determination of Enantiomeric Excess
(2014-07)Circular dichroism (CD) spectropolarimeters typically employ one photoelastic modulator. However, spectropolarimeters employing two or even four modulators are more versatile and can be used to subvert common measurement ... -
Mechanistic Studies on Covalent Assemblies of Metal-Mediated Hemi-Aminal Ethers
(2015-09)The use of reversible covalent bonding in a four-component assembly incorporating chiral alcohols was recently reported to give a method for determining the enantiomeric excess of the alcohols via CD spectroscopy. Experiments ... -
Structural Characterization of Holo- and Apo-Myoglobin in the Gas Phase by Ultraviolet Photodissociation Mass Spectrometry
(2015-11)Ultraviolet photodissociation (UVPD) mass spectrometry is employed to investigate the structure of holo-myoglobin as well as its apo form transferred to the gas phase by native electrospray. UVPD provided insight into the ... -
Ion Pair-Induced Conformational Motion in Calix 4 Arene-Strapped Calix 4 Pyrroles
(2015-12)In order to understand the still-poorly understood interplay between calix[4]arene conformations and cation and anion recognition in multicomponent systems, the ion pair receptors 1 and 2 were synthesized. In solution and ... -
Reaction-Based Indicator Displacement Assay (RIA) for the Selective Colorimetric and Fluorometric Detection of Peroxynitrite
(2015-03)Using the self-assembly of aromatic boronic acids with Alizarin Red S (ARS), we developed a new chemosensor for the selective detection of peroxynitrite. Phenylboronic acid (PBA), benzoboroxole (BBA) and 2-(N, N-dimethyl ... -
From Monomers to Polymers: Steric and Supramolecular Effects on Dimensionality of Coordination Architectures of Heteroleptic Mercury(II) Halogenide-Tetradentate Schiff Base Complexes
(2015-03)In this study, neutral mercury(II) complexes of the composition [Hg(L1)(mu-Cl)(2)Hg3Cl6](n) (1), [Hg(L1)(mu-Br)(2)HgBr2] (2), [Hg(L3)Br-2] (2a), [Hg(L1)I-2] (3), [Hg(L2)Cl-2]center dot CH3OH (4) and [Hg(L2)(mu-Br)HgBr3](2) ... -
A Chemistry and Material Perspective On Lithium Redox Flow Batteries Towards High-Density Electrical Energy Storage
(2015-11)Electrical energy storage system such as secondary batteries is the principle power source for portable electronics, electric vehicles and stationary energy storage. As an emerging battery technology, Li-redox flow batteries ... -
Nanostructured Conductive Polymers for Advanced Energy Storage
(2015-05)Conductive polymers combine the attractive properties associated with conventional polymers and unique electronic properties of metals or semiconductors. Recently, nanostructured conductive polymers have aroused considerable ... -
Understanding Ferroelectricity in Layered Perovskites: New Ideas and Insights from Theory and Experiments
(2015-06)ABO(3) perovskites have fascinated solid-state chemists and physicists for decades because they display a seemingly inexhaustible variety of chemical and physical properties. However, despite the diversity of properties ...
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