Dynamic 2D Manganese(II) Isonicotinate Framework with Reversible Crystal-To-Amorphous Transformation and Selective Guest Adsorption
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Date
2014-04
Authors
Matoga, Dariusz
Gil, Barbara
Nitek, Wojciech
Todd, Alexander D.
Bielawski, Christopher W.
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Abstract
A 2D layered microporous isonicotinate-supported manganese(II) metal-organic framework was found to exhibit a reversible crystalto-amorphous transformation upon the removal and uptake of certain guest molecules. Unsaturated metal centers, generated in the dynamic framework upon activation, were found to facilitate the selective adsorption of CO2 versus N-2.
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Matoga, Dariusz, Barbara Gil, Wojciech Nitek, Alexander D. Todd, and Christopher W. Bielawski. "Dynamic 2D manganese (II) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption." CrystEngComm 16, no. 23 (Apr., 2014): 4959-4962.