Heteronuclear Trimetallic and 1D Polymeric 3D-4F Schiff Base Complexes with OCN- and SCN- Ligands

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dc.contributor.utaustinauthorJones, Richard A.en_US
dc.creatorZhao, Shunshengen_US
dc.creatorLu, Xingqiangen_US
dc.creatorHou, Anxinen_US
dc.creatorWong, Wai-Yeungen_US
dc.creatorWong, Wai-Kwoken_US
dc.creatorYang, Xiaopingen_US
dc.creatorJones, Richard A.en_US
dc.date.accessioned2016-09-23T18:05:34Z
dc.date.available2016-09-23T18:05:34Z
dc.date.issued2009-09en_US
dc.description.abstractReactions of heterobimetallic 3d-4f Schiff base complexes of the formula [ZnLnL(H2O)(NO3)(3)] (1a-e) with KOCN or NH4SCN in refluxing MeCN produce either one dimensional polymeric materials [ZnLnL(NO3)(2)(H2O)(OCN)](infinity) (2a-c) or trinuclear complexes of the formula [Zn(2)LnL(2)(NO3)(SCN)(2)] (3a-e)(a(La), b(Nd), c(Er), d(Tb), e(Eu); H2L = N, N'-bis-(3-methoxysalicylidene)ethylene-1,2-diamine). The structures of 2a,b and 3b-e have been determined by single-crystal X-ray diffraction studies. Structural differences between the complexes affect the photophysical properties, which have been studied in acetonitrile solutions.en_US
dc.description.departmentChemistryen_US
dc.description.sponsorshipHong Kong Baptist University FRG/06-07/II-16en_US
dc.description.sponsorshipHong Kong Research Grants Council HKBU 202407en_US
dc.description.sponsorshipRobert A. Welch Foundation F-816en_US
dc.description.sponsorshipTexas Higher Education Coordinating Board ARP 003658-0010-2006en_US
dc.description.sponsorshipPetroleum Research Fund, administered by the American Chemical Society 47014-AC5en_US
dc.identifierdoi:10.15781/T2SX64B4V
dc.identifier.citationZhao, Shunsheng, Xingqiang Lü, Anxin Hou, Wai-Yeung Wong, Wai-Kwok Wong, Xiaoping Yang, and Richard A. Jones. "Heteronuclear trimetallic and 1D polymeric 3d–4f Schiff base complexes with OCN? and SCN? ligands." Dalton Transactions 43 (Sep., 2009): 9595-9602.en_US
dc.identifier.doi10.1039/b908682jen_US
dc.identifier.issn1477-9226en_US
dc.identifier.urihttp://hdl.handle.net/2152/41065
dc.language.isoEnglishen_US
dc.relation.ispartofen_US
dc.relation.ispartofserialDalton Transactionsen_US
dc.rightsAdministrative deposit of works to Texas ScholarWorks: This works author(s) is or was a University faculty member, student or staff member; this article is already available through open access or the publisher allows a PDF version of the article to be freely posted online. The library makes the deposit as a matter of fair use (for scholarly, educational, and research purposes), and to preserve the work and further secure public access to the works of the University.en_US
dc.rights.restrictionOpenen_US
dc.subjectnear-infrared luminescenceen_US
dc.subjectenergy-transferen_US
dc.subjectlanthanide luminescenceen_US
dc.subjectphotophysical propertiesen_US
dc.subjectcrystal-structuresen_US
dc.subjectbuilding-blocksen_US
dc.subjecter3+en_US
dc.subjectcomplexesen_US
dc.subjectnden_US
dc.subjectemissionen_US
dc.subjectsensitizationen_US
dc.subjectchemistry, inorganic & nuclearen_US
dc.titleHeteronuclear Trimetallic and 1D Polymeric 3D-4F Schiff Base Complexes with OCN- and SCN- Ligandsen_US
dc.typeArticleen_US

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