Synthesis and Structures of Mononuclear 3,4-Bis(Trifluoromethyl)Pyrrolyl Complexes of Rh(I) and Ni(II)
| dc.contributor.utaustinauthor | Rivers, Joseph H. | en_US |
| dc.contributor.utaustinauthor | Jones, Richard A. | en_US |
| dc.creator | Rivers, Joseph H. | en_US |
| dc.creator | Jones, Richard A. | en_US |
| dc.date.accessioned | 2016-09-23T18:04:38Z | |
| dc.date.available | 2016-09-23T18:04:38Z | |
| dc.date.issued | 2014-11 | en_US |
| dc.description.abstract | New mononuclear complexes of the 3,4-bis(trifluoromethyl)pyrrolyl ligand (3,4-(CF3)(2)-Pyr(-)) with Rh(I) and Ni(II) are reported. Reaction of 3,4-(CF3)(2)-PyrNa with [Rh(COD)Cl](2) produces [Rh(PMe3)(3)(3,4-(CF3)(2)(-)Pyr)] (1) while reaction of 3,4-(CF3)(2)-PyrH with [Ni(PMe3)(2)Me-2] (2) or [Ni(PMe3)(2)Ph-2] (4) gives [trans-Ni (PMe3)(2) (3,4-(CF3)(2)-Pyr)(CH3)] (3) or [trans-Ni(PMe3)(2)(C6H5)(3,4-(CF3)2-Pyr)] (5) respectively. Complexes 1, 3 and 5 have been characterized spectroscopically and all five compounds have been structurally characterized by single crystal X-ray diffraction studies. | en_US |
| dc.description.department | Chemistry | en_US |
| dc.description.sponsorship | Welch Foundation F-816 | en_US |
| dc.description.sponsorship | Petroleum Research Fund 47014-ACS | en_US |
| dc.description.sponsorship | NSF 0741973 | en_US |
| dc.identifier | doi:10.15781/T2NK3663K | |
| dc.identifier.citation | Rivers, Joseph H., and Richard A. Jones. "Synthesis and structures of mononuclear 3, 4-bis (trifluoromethyl) pyrrolyl complexes of Rh (I) and Ni (II)" Dalton Transactions 43, no. 43 (Nov., 2014): 16275-16282. | en_US |
| dc.identifier.doi | 10.1039/c4dt01742k | en_US |
| dc.identifier.issn | 1477-9226 | en_US |
| dc.identifier.uri | http://hdl.handle.net/2152/41012 | |
| dc.language.iso | English | en_US |
| dc.relation.ispartof | en_US | |
| dc.relation.ispartofserial | Dalton Transactions | en_US |
| dc.rights | Administrative deposit of works to Texas ScholarWorks: This works author(s) is or was a University faculty member, student or staff member; this article is already available through open access or the publisher allows a PDF version of the article to be freely posted online. The library makes the deposit as a matter of fair use (for scholarly, educational, and research purposes), and to preserve the work and further secure public access to the works of the University. | en_US |
| dc.rights.restriction | Open | en_US |
| dc.subject | molybdenum imido alkylidene | en_US |
| dc.subject | n-h bond | en_US |
| dc.subject | pyrrolyl complexes | en_US |
| dc.subject | molecular-structure | en_US |
| dc.subject | cvd precursors | en_US |
| dc.subject | ligands | en_US |
| dc.subject | polymerization | en_US |
| dc.subject | tungsten | en_US |
| dc.subject | catalysts | en_US |
| dc.subject | crystal | en_US |
| dc.subject | chemistry, inorganic & nuclear | en_US |
| dc.title | Synthesis and Structures of Mononuclear 3,4-Bis(Trifluoromethyl)Pyrrolyl Complexes of Rh(I) and Ni(II) | en_US |
| dc.type | Article | en_US |