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dc.creatorLynch, Vincent M.en
dc.creatorLee, W. C.en
dc.creatorMartin, Stephen F.en
dc.creatorDavis, Brian E.en
dc.date.accessioned2015-09-09T15:50:35Zen
dc.date.available2015-09-09T15:50:35Zen
dc.date.issued1991-05en
dc.identifier.citationLynch, Vincent M., Lee, W. C., Martin, Stephen F., Davis, Brian E. >Structure of a fully protected seco-erythronolide B acid derivative,> Acta Crystallogr C. 1991 May 15;47 ( Pt 5):1117-20. doi: 10.1107/S0108270190012008en
dc.identifier.issn0108-2701en
dc.identifier.urihttp://hdl.handle.net/2152/31104en
dc.description.abstract(3S,4R,5S,6R,7R,9R,10S,11S,12S,13S,14R)-14-Benzyloxymethoxy-10,12-O-carbonyl-4-N-imidazolycarbonyl-6,7-O-isopropylidene-3,5,7,9,11,-13-hexamethylhexadec-1-ene-4,6,7,10,12,14-hexol, C38H56N2O9, M(r) = 684.87, monoclinic, P2(1), a = 8.7302 (12), b = 15.597 (2), c = 14.463 (2) angstrom, beta = 104.797 (10)degrees, V = 1904.1 (4) angstrom 3, Z = 2, D(x) (198 K) = 1.19 g cm-3, mu = 0.7893 cm-1, Mo K-alpha radiation, lambda = 0.7107 angstrom, F(000) = 740, T = 198 K, R = 0.0301 for 3141 reflections [F(o) greater-than-or-equal-to 4-sigma(F(o))]. The crystal structure was undertaken to determine the stereochemistry of the title compound. The molecule is folded on itself in such a way that the portion of the molecule from the phenyl ring at C44 and extending to C28 forms nearly a single turn of a right-handed screw. Large deviations from ideality for several Csp3-Csp3 bond angles are observed that are presumably due to intramolecular steric effects. The largest deviations are: C3-C4-C5 117.8 (2), C5-C6-C7 121.2 (2), C7-C8-C9 115.3 (2), C9-C10-C11 116.2 (2), C11-C12-C13 117.2 (2), C14-C15-C16 115.5 (3)degrees.en
dc.description.sponsorshipRobert A. Welch Foundation (F-652)en
dc.description.sponsorshipNational Institutes of Health (GM 31077)en
dc.language.isoEnglishen
dc.rightsAdministrative deposit of works to Texas ScholarWorks: This works author(s) is or was a University faculty member, student or staff member; this article is already available through open access or the publisher allows a PDF version of the article to be freely posted online. The library makes the deposit as a matter of fair use (for scholarly, educational, and research purposes), and to preserve the work and further secure public access to the works of the University.en
dc.subjectcrystallographyen
dc.titleStructure Of A Fully Protected Seco-Erythronolide B-Acid Derivativeen
dc.typeNoteen
dc.rights.holderen
dc.description.departmentChemistryen
dc.description.departmentBiochemistryen
dc.identifier.doi10.1107/s0108270190012008en
dc.identifier.urlen
dc.contributor.utaustinauthorLynch, Vincent M.en
dc.contributor.utaustinauthorLee, W. C.en
dc.contributor.utaustinauthorMartin, Stephen F.en
dc.contributor.utaustinauthorDavis, Brian E.en
dc.relation.ispartofserialActa Crystallographica Section C-Crystal Structure Communicationsen


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