Modelling and control of reactive distillation for alkylation reactions

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dc.contributor.advisorEdgar, Thomas F.
dc.contributor.advisorEldridge, R. Bruce
dc.creatorSchell, John R.en
dc.date.accessioned2015-02-13T20:06:25Zen
dc.date.available2015-02-13T20:06:25Zen
dc.date.issued2002-05en
dc.descriptiontexten
dc.description.abstractA reactive distillation column for the alkylation of benzene with long chain linear olefin was studied. The study involved design, construction, experimentation, and simulation of the column. Establishing the design required study of reaction rates, thermodynamic relationships, and packing structures. A heuristic was developed for the design of such columns. This heuristic involved estimating an amount of catalyst loading and subsequently determining the operating parameters for a column. This method is particularly applicable to systems with high concentrations of inert feeds. A column was constructed following the design. Data was collected from the column and compared to simulations. The simulations were performed with Aspen Plus RADFRAC. In this manner, the data was used to validate the commercial steady state models for reactive distillation. In addition, dynamic simulations of the system were performed. These dynamic simulations provided insight into more design considerations. For example, steady state simulations indicated an optimal feed stage based on steady state conversion of the olefin. However, the dynamic simulations showed a potential disadvantage to the utilization of the optimal feed stage. With some disturbances, a column configured with the feed stage with the highest steady state conversion also deviated from the steady state faster and with greater amplitude than other configurations. These considerations were further explored in developing a control scheme for reactive distillation columns. Control of reactive distillation differs from traditional distillation in that one control variable is conversion. Traditional distillation generally focuses on production rates and product purity. To this end, control schemes were analyzed and dynamic simulations were performed. These simulations showed an advantage to a variable pairing in which duty is paired with conversion. The conversion was inferred from a stage temperature in the reactive zone. In addition, distillate rate may be paired with product composition. In conclusion, the reactive distillation column design for long chain olefin alkylation of benzene requires careful estimation of catalyst requirements and valid simulation tools. In addition, dynamic response should be considered in the design. Finally, a simple inferential control scheme may be adequate.en
dc.description.departmentChemical Engineeringen
dc.format.mediumelectronicen
dc.identifier.urihttp://hdl.handle.net/2152/28460en
dc.language.isoengen
dc.rightsCopyright is held by the author. Presentation of this material on the Libraries' web site by University Libraries, The University of Texas at Austin was made possible under a limited license grant from the author who has retained all copyrights in the works.en
dc.rights.restrictionRestricteden
dc.subjectReactive distillation columnsen
dc.subjectAlkylationen
dc.subjectBenezeneen
dc.subjectLong chain linear olefinen
dc.titleModelling and control of reactive distillation for alkylation reactionsen
dc.typeThesisen
thesis.degree.departmentChemical Engineeringen
thesis.degree.disciplineChemical Engineeringen
thesis.degree.grantorThe University of Texas at Austinen
thesis.degree.levelDoctoralen
thesis.degree.nameDoctor of Philosophyen

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