Browsing by Subject "Actinide"
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Item The development of hexaphyrin-expanded porphyrins and deferasirox derivatives for their applications toward f-element coordination(2022-12-02) Mangel, Daniel Nathan; Sessler, Jonathan L.; Anslyn, Eric V; Henkelman, Graeme; Forgione, PatExpanded porphyrins are versatile ligands that allow a multitude of coordination modes. Modification of the porphyrin core and the pendant substituents have extended the coordination chemistry of expanded porphyrins to include systems that stabilize f-element metal complexes. In this dissertation, I detail my efforts to expand the f-element coordination to hexaphyrin-expanded porphyrins with in-depth, theoretical, and experimental. In addition, I will describe my efforts at developing a novel lanthanide chelator that exhibits high lutetium selectivity.