CO2 Adsorption Properties of a Ca(II)-Based Organophosphonium Coordination Material
| dc.contributor.utaustinauthor | Ibarra, Ilich A. | en_US |
| dc.contributor.utaustinauthor | Tan, Kristina E. | en_US |
| dc.contributor.utaustinauthor | Lynch, Vincent M. | en_US |
| dc.contributor.utaustinauthor | Humphrey, Simon M. | en_US |
| dc.creator | Ibarra, Ilich A. | en_US |
| dc.creator | Tan, Kristina E. | en_US |
| dc.creator | Lynch, Vincent M. | en_US |
| dc.creator | Humphrey, Simon M. | en_US |
| dc.date.accessioned | 2016-09-23T18:05:12Z | |
| dc.date.available | 2016-09-23T18:05:12Z | |
| dc.date.issued | 2012-01 | en_US |
| dc.description.abstract | PCM-14 is a dense coordination polymer formed from Ca(II) and an unusual organophosphonium ligand. The dehydrated framework contains 3-coordinate Ca(II) sites within catenated, chiral 3,3-connected nets. PCM-14 exhibits a stark CO2 sorption selectivity over H-2, N-2 and O-2. The maximum CO2 uptake was shown to be highly sensitive to the material pretreatment evacuation temperature. | en_US |
| dc.description.department | Chemistry | en_US |
| dc.description.sponsorship | Welch Foundation F-1738 | en_US |
| dc.identifier | doi:10.15781/T2HM52M16 | |
| dc.identifier.citation | Ibarra, Ilich A., Kristina E. Tan, Vincent M. Lynch, and Simon M. Humphrey. "CO 2 adsorption properties of a Ca (ii)-based organophosphonium coordination material." Dalton Transactions 41, no. 14 (Jan., 2012): 3920-3923. | en_US |
| dc.identifier.doi | 10.1039/c2dt12011a | en_US |
| dc.identifier.issn | 1477-9226 | en_US |
| dc.identifier.uri | http://hdl.handle.net/2152/41044 | |
| dc.language.iso | English | en_US |
| dc.relation.ispartof | en_US | |
| dc.relation.ispartofserial | Dalton Transactions | en_US |
| dc.rights | Administrative deposit of works to Texas ScholarWorks: This works author(s) is or was a University faculty member, student or staff member; this article is already available through open access or the publisher allows a PDF version of the article to be freely posted online. The library makes the deposit as a matter of fair use (for scholarly, educational, and research purposes), and to preserve the work and further secure public access to the works of the University. | en_US |
| dc.rights.restriction | Open | en_US |
| dc.subject | metal-organic framework | en_US |
| dc.subject | structural-characterization | en_US |
| dc.subject | hydrogen | en_US |
| dc.subject | exchange | en_US |
| dc.subject | sites | en_US |
| dc.subject | pore | en_US |
| dc.subject | chemistry, inorganic & nuclear | en_US |
| dc.title | CO2 Adsorption Properties of a Ca(II)-Based Organophosphonium Coordination Material | en_US |
| dc.type | Article | en_US |