Synthesis and Characterization of A Tetrathiafulvalene-Salphen Actinide Complex
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Date
2013-03
Authors
Bejger, Christopher
Tian, Yong-Hui
Barker, Beau J.
Boland, Kevin S.
Scott, Brian L.
Batista, Enrique R.
Kozimor, Stosh A.
Sessler, Jonathan L.
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Abstract
A new tetrathiafulvalene-salphen uranyl complex has been prepared. The system was designed to study the electronic coupling between actinides and a redox active ligand framework. Theoretical and experimental methods - including DFT calculations, single crystal X-ray analysis, cyclic voltammetry, NMR and IR spectroscopies - were used to characterize this new uranyl complex.
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Bejger, Christopher, Yong-Hui Tian, Beau J. Barker, Kevin S. Boland, Brian L. Scott, Enrique R. Batista, Stosh A. Kozimor, and Jonathan L. Sessler. "Synthesis and characterization of a tetrathiafulvalene-salphen actinide complex." Dalton Transactions 42, no. 19 (Mar., 2013): 6716-6719.