Synthesis, Characterization, and Photophysical Properties of a Thiophene-Functionalized Bis(Pyrazolyl) Pyridine (BPP) Tricarbonyl Rhenium(I) Complex

dc.contributor.utaustinauthorLytwak, Lauren A.en_US
dc.contributor.utaustinauthorStanley, Julie M.en_US
dc.contributor.utaustinauthorMejia, Michelle L.en_US
dc.contributor.utaustinauthorHolliday, Bradley J.en_US
dc.creatorLytwak, Lauren A.en_US
dc.creatorStanley, Julie M.en_US
dc.creatorMejia, Michelle L.en_US
dc.creatorHolliday, Bradley J.en_US
dc.date.accessioned2016-09-23T18:05:26Z
dc.date.available2016-09-23T18:05:26Z
dc.date.issued2010-06en_US
dc.description.abstractA bromo tricarbonyl rhenium(I) complex with a thiophene-functionalized bis(pyrazolyl) pyridine ligand (L), ReBr(L)(CO)(3) (1), has been synthesized and characterized by variable temperature and COSY 2-D H-1 NMR spectroscopy, single-crystal X-ray diffraction, and photophysical methods. Complex 1 is highly luminescent in both solution and solid-state, consistent with phosphorescence from an emissive (MLCT)-M-3 excited state with an additional contribution from a LC (3)(pi ->pi*) transition. The single-crystal X-ray diffraction structure of the title ligand is also reported.en_US
dc.description.departmentChemistryen_US
dc.description.sponsorshipRobert A. Welch Foundation F-1631en_US
dc.description.sponsorshipPetroleum Research Fund 47022-G3en_US
dc.description.sponsorshipNational Science Foundation CHE-0639239, CHE-0741973, CHE-0847763en_US
dc.description.sponsorshipAmerican Heart Association 0765078Yen_US
dc.description.sponsorshipUT-CNMen_US
dc.description.sponsorshipUT-Austinen_US
dc.identifierdoi:10.15781/T2Q52FF08
dc.identifier.citationLytwak, Lauren A., Julie M. Stanley, Michelle L. Mejía, and Bradley J. Holliday. "Synthesis, characterization, and photophysical properties of a thiophene-functionalized bis (pyrazolyl) pyridine (BPP) tricarbonyl rhenium (I) complex." Dalton Transactions 39, no. 33 (Jun., 2010): 7692-7699.en_US
dc.identifier.doi10.1039/c0dt00357cen_US
dc.identifier.issn1477-9226en_US
dc.identifier.urihttp://hdl.handle.net/2152/41058
dc.language.isoEnglishen_US
dc.relation.ispartofen_US
dc.relation.ispartofserialDalton Transactionsen_US
dc.rightsAdministrative deposit of works to Texas ScholarWorks: This works author(s) is or was a University faculty member, student or staff member; this article is already available through open access or the publisher allows a PDF version of the article to be freely posted online. The library makes the deposit as a matter of fair use (for scholarly, educational, and research purposes), and to preserve the work and further secure public access to the works of the University.en_US
dc.rights.restrictionOpenen_US
dc.subjectligand charge-transferen_US
dc.subjectlight-emitting materialsen_US
dc.subjectlowest excited-stateen_US
dc.subjectcrystal-structure determinationen_US
dc.subjecttransition-metal-complexesen_US
dc.subjectprotein-binding propertiesen_US
dc.subjectorganometallic complexesen_US
dc.subjectdiimine complexesen_US
dc.subjectspectroscopic characterizationen_US
dc.subjectelectrophosphorescent devicesen_US
dc.subjectchemistry, inorganic & nuclearen_US
dc.titleSynthesis, Characterization, and Photophysical Properties of a Thiophene-Functionalized Bis(Pyrazolyl) Pyridine (BPP) Tricarbonyl Rhenium(I) Complexen_US
dc.typeArticleen_US

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