A Copper-Polyol Complex: Na-2(C2H6O2)(6) Cu(C2H4O2)(2)

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Date

2010-03

Authors

Rivers, Joseph H.
Carroll, Kyler J.
Jones, Richard A.
Carpenter, Everett E.

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Abstract

The ionic title complex, bis(mu-ethylene glycol)-kappa O-3,O':O';- kappa O-3:O,O'-bis[(ethylene glycol-kappa O-2,O')(ethylene glycol-kappa O)-sodium] bis(ethylene glycolato-kappa O-2,O')copper(II), [Na-2(C2H6O2)(6)][Cu(C2H4O2)(2)], was obtained from a basic solution of CuCl2 in ethylene glycol and consists of discrete ions interconnected by O-H center dot center dot center dot O hydrogen bonds. This is the first example of a disodium-ethylene glycol complex cation cluster. The cation lies about an inversion center and the Cu II atom of the anion lies on another independent inversion center.

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Rivers, Joseph H., Carroll, Kyler J., Jones, Richard A., Carpenter, Everett E., >A copper-polyol complex: [Na2(C2H6O2)6][Cu(C2H4O2)2],> Acta Crystallogr C. 2010 Mar;66(Pt 3):m83-5. doi: 10.1107/S0108270110006311. Epub 2010 Feb 24. doi: 10.1107/S0108270110006311