Non-Cyclic Formylated Dipyrromethanes as Phosphate Anion Receptors

dc.contributor.utaustinauthorDeliomeroglu, Murat K.en_US
dc.contributor.utaustinauthorLynch, Vincent M.en_US
dc.contributor.utaustinauthorSessler, Jonathan L.en_US
dc.creatorDeliomeroglu, Murat K.en_US
dc.creatorLynch, Vincent M.en_US
dc.creatorSessler, Jonathan L.en_US
dc.date.accessioned2016-09-23T18:07:19Z
dc.date.available2016-09-23T18:07:19Z
dc.date.issued2016-02en_US
dc.description.abstractNew tetrakis-and hexakis(H-1-pyrrole-2-carbaldehyde) anion receptors are described. The anion binding properties of these receptors were studied in organic media and in the solid state. The receptors displayed good affinity for the dihydrogenphosphate and pyrophosphate anions (as the tetrabutylammonium salts) in chloroform even in the presence of a polar protic solvent, methanol. Solution phase spectroscopic analyses proved consistent with the binding mode seen in single crystal structural studies of the dihydrogenphosphate and pyrophosphate complexes and provided support for the contention that these receptors undergo conformational reorganization in order to accommodate the bound oxoanions both in chloroform solution and in the solid state.en_US
dc.description.departmentChemistryen_US
dc.description.sponsorshipOffice of Basic Energy Sciences, U.S. Department of Energy (DOE) DE-FG02-01ER15186en_US
dc.identifierdoi:10.15781/T2222R72B
dc.identifier.citationDeliomeroglu, Murat K., Vincent M. Lynch, and Jonathan L. Sessler. "Non-cyclic formylated dipyrromethanes as phosphate anion receptors." Chemical Science 7, no. 6 (Feb., 2016): 3843-3850.en_US
dc.identifier.doi10.1039/c6sc00015ken_US
dc.identifier.issn2041-6520en_US
dc.identifier.urihttp://hdl.handle.net/2152/41156
dc.language.isoEnglishen_US
dc.relation.ispartofen_US
dc.relation.ispartofserialChemical Scienceen_US
dc.rightsAdministrative deposit of works to Texas ScholarWorks: This works author(s) is or was a University faculty member, student or staff member; this article is already available through open access or the publisher allows a PDF version of the article to be freely posted online. The library makes the deposit as a matter of fair use (for scholarly, educational, and research purposes), and to preserve the work and further secure public access to the works of the University.en_US
dc.rights.restrictionOpenen_US
dc.subjection-pair receptoren_US
dc.subjectbinding agentsen_US
dc.subjectrecognitionen_US
dc.subjectsapphyrinen_US
dc.subjectmoleculesen_US
dc.subjectwateren_US
dc.subjectolden_US
dc.subjectchemistry, multidisciplinaryen_US
dc.titleNon-Cyclic Formylated Dipyrromethanes as Phosphate Anion Receptorsen_US
dc.typeArticleen_US

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