Photoelectrochemical ion concentration polarization : a microfluidic ion filtration system using light-driven electrochemical reactions

dc.contributor.advisorCrooks, Richard M. (Richard McConnell)
dc.creatorYoon, Eunsoo
dc.date.accessioned2019-08-23T21:01:44Z
dc.date.available2019-08-23T21:01:44Z
dc.date.created2017-05
dc.date.issued2017-06-26
dc.date.submittedMay 2017
dc.date.updated2019-08-23T21:01:45Z
dc.description.abstractWe report an ion separation or filtration method used in microchannel called photoelectrochemical ion concentration polarization (pICP). As a variant of faradaic ion concentration polarization (fICP), pICP utilizes TiO₂ photoelectrochemistry to form an ion depletion zone (IDZ) with light. A microfluidic device with TiO₂ photoanode and Pt cathode generated IDZ near the cathode by generating a corresponding electrochemical reaction. Local electric field near the cathode was amplified with TiO₂ irradiation. Furthermore, on-chip solution conductivity measurement confirmed decrease in ion concentration as a consequence of pICP ion filtration.
dc.description.departmentChemistry
dc.format.mimetypeapplication/pdf
dc.identifier.urihttps://hdl.handle.net/2152/75659
dc.identifier.urihttp://dx.doi.org/10.26153/tsw/2763
dc.subjectPhotoelectrochemical
dc.subjectIon concentration polarization
dc.subjectMicrofluidic
dc.subjectIon separation
dc.titlePhotoelectrochemical ion concentration polarization : a microfluidic ion filtration system using light-driven electrochemical reactions
dc.typeThesis
dc.type.materialtext
thesis.degree.departmentChemistry
thesis.degree.disciplineChemistry
thesis.degree.grantorThe University of Texas at Austin
thesis.degree.levelMasters
thesis.degree.nameMaster of Arts

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