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    Method of cleaving DNA

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    US5672490.pdf (5.741Mb)
    Date
    1997-09-30
    Author
    Richard E. Thomas
    Jonathan L. Sessler
    Brent L. Iverson
    Vladimir A. Kral
    Kevin Shreder
    Hiroyuki Furuta
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    Abstract
    The present invention provides various novel covalently modified sapphyrin derivatives and conjugates; polymers including sapphyrin or derivatives thereof; and chromatographic supports including sapphyrins and other expanded porphyrins and derivatives thereof. Disclosed are water soluble sapphyrins, including polyhydroxysapphyrins and sapphyrin-sugar derivatives; sapphyrin-metal chelating conjugates; sapphyrin nucleobase conjugates; oligosapphyrins and polysapphyrins, including sapphyrin dimers, trimers, oligomers and higher polymers; and polymer supported expanded porphyrin compositions, including advantageous rubyrin- and sapphyrin-based chromatography columns and electrophoretic supports. Sapphyrin oligomers and polymers and polymer supported expanded porphyrins, such as, e.g., glass and silica expanded porphyrin constructs, are disclosed which include both repeating units of sapphyrin derivatives alone and which include other units, for example, nucleobases, sapphyrin-nucleobase conjugates and long chain alkyl groups.
    Department
    Board of Regents, University of Texas System
    URI
    https://hdl.handle.net/2152/77107
    http://dx.doi.org/10.26153/tsw/4196
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