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    Method of expanded porphyrin-oligonucleotide conjugate synthesis

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    US5565552.pdf (1.581Mb)
    Date
    1996-10-15
    Author
    Jonathan L. Sessler
    Brent L. Iverson
    Shaun P. Crofts
    Darren Magda
    Petra I. Sansom
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    Abstract
    The invention is directed to a method of incorporating expanded porphyrins, and particularly of incorporating a sapphyrin or a texaphyrin, before, during, or after chemical synthesis of an oligomer to form an expanded porphyrin-oligonucleotide conjugate, and particularly a sapphyrin- or texaphyrin-oligonucleotide conjugate. This method includes reacting derivatized nucleotides and a sapphyrin or a texaphyrin in a desired order in an automated or manual DNA synthesizer having a solid support to form a sapphyrin- or a texaphyrin-oligonucleotide conjugate.
    Department
    Board of Regents, University of Texas System
    URI
    https://hdl.handle.net/2152/76623
    http://dx.doi.org/10.26153/tsw/3712
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