Syntheses, Structures, and Photoluminescence of 1-D Lanthanide Coordination Polymers

Five new lanthanide 1-D coordination polymers are reported which are formed from flexible salen type Schiff-base ligands H(2)L and H(2)L' (H(2)L = N, N(1)-ethylene bis(salicylideneimine); H(2)L' = N,N(1)-bis(3-methoxysalicylidene) ethylene-1,2-diamine). The polymeric structures are formed by bridging neutral H(2)L units in the case of {[Ln(2)L(2)(CF(3)SO(3))(H(2)L)(4)(MeOH)]center dot CF(3)SO(3)}(n) (Ln = Eu (1), Nd (2) and Er (3)), and by acetate (OAc(-)) groups in Yb(2)(L)(2)(OAc)(2)(MeOH)(2) (4) and {[Tb(3)(L')(2)(OAc)(5)]center dot Et(2)O center dot(MeOH)(0.5)}(n) (5). The structures of 1-5 were determined by single crystal X-ray crystallographic studies and the luminescence properties of 1 and 5 in MeOH solution were determined.