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    Construction of 1-D 4F and 3D-4F Coordination Polymers with Flexible Schiff Base Ligands

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    2011_Yang.pdf (748.9Kb)
    Date
    2011-07
    Author
    Yang, Xiaoping
    Lam, Daniel
    Chan, Christopher
    Stanley, Julie M.
    Jones, Richard A.
    Holliday, Bradley J.
    Wong, Wai-Kwok
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    Abstract
    Three new lanthanide 1-D coordination polymers ({[Ln(2)(H2L)(OAc)(6)]center dot EtOH center dot 2H(2)O}(n) (Ln = Eu (1), Er (2)) and {YbNiLCl(OAc)(2)(H2O)}(n) (3)) and a heterobinuclear complex [YbNiLCl3(H2O)(3)] (4) are reported which are formed from salen type Schiff-base ligands H2L (H2L = N,N'-bis(3-methoxysalicylidene) butane-1,4-diamine). The polymeric structures are formed by bridging H2L units in the case of 1 and 2, and by acetate groups in 3. The structures of 1-4 were determined by single crystal X-ray crystallographic studies and their luminescence properties in MeCN solution were determined.
    Department
    Chemistry
    Subject
    metal-organic frameworks
    lanthanide complexes
    magnetic-properties
    adsorption properties
    solid-state
    luminescence
    design
    3d
    architecture
    diversity
    chemistry, inorganic & nuclear
    URI
    http://hdl.handle.net/2152/41053
    Citation
    Yang, Xiaoping, Daniel Lam, Christopher Chan, Julie M. Stanley, Richard A. Jones, Bradley J. Holliday, and Wai-Kwok Wong. "Construction of 1-D 4f and 3d–4f coordination polymers with flexible Schiff base ligands." Dalton Transactions 40, no. 38 (Jul., 2011): 9795-9801.
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