Dynamic 2D Manganese(II) Isonicotinate Framework with Reversible Crystal-To-Amorphous Transformation and Selective Guest Adsorption

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Date

2014-04

Authors

Matoga, Dariusz
Gil, Barbara
Nitek, Wojciech
Todd, Alexander D.
Bielawski, Christopher W.

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Abstract

A 2D layered microporous isonicotinate-supported manganese(II) metal-organic framework was found to exhibit a reversible crystalto-amorphous transformation upon the removal and uptake of certain guest molecules. Unsaturated metal centers, generated in the dynamic framework upon activation, were found to facilitate the selective adsorption of CO2 versus N-2.

Department

Chemistry

Description

Keywords

metal-organic frameworks, hydrogen storage properties, mn2+ coordination, sites, magnetic-properties, gas-adsorption, co2 capture, separation, stability, alcohols, channels, chemistry, multidisciplinary, crystallography

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Citation

Matoga, Dariusz, Barbara Gil, Wojciech Nitek, Alexander D. Todd, and Christopher W. Bielawski. "Dynamic 2D manganese (II) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption." CrystEngComm 16, no. 23 (Apr., 2014): 4959-4962.

URI

http://hdl.handle.net/2152/41015

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