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dc.creatorSaberov, Vagiz Sh.en_US
dc.creatorEvans, Daniel A.en_US
dc.creatorKorotkikh, Nikolai I.en_US
dc.creatorCowley, Alan H.en_US
dc.creatorPekhtereva, Tatyana M.en_US
dc.creatorPopov, Anatolii F.en_US
dc.creatorShvaika, Oles P.en_US
dc.date.accessioned2016-09-23T18:04:36Z
dc.date.available2016-09-23T18:04:36Z
dc.date.issued2014-10en_US
dc.identifierdoi:10.15781/T2X05XD8R
dc.identifier.citationSaberov, Vagiz Sh, Daniel A. Evans, Nikolai I. Korotkikh, Alan H. Cowley, Tatyana M. Pekhtereva, Anatolii F. Popov, and Oles P. Shvaika. "Exceptionally efficient catalytic hydrodechlorination of persistent organic pollutants: application of new sterically shielded palladium carbene complexes." Dalton Transactions 43, no. 48 (Oct., 2014): 18117-18122.en_US
dc.identifier.issn1477-9226en_US
dc.identifier.urihttp://hdl.handle.net/2152/41010
dc.description.abstractA new sterically shielded carbene with branched aromatic substituents (9a) and two palladium halogenide complexes have been prepared. The single crystal X-ray structures of free carbene 9a and palladium carbene complexes 10b and 11a were determined. Very high catalytic efficiencies were evident for the sterically shielded palladium carbene complexes 10b and 11a,b when the latter complexes were employed as catalysts for hydrodechlorination of the chloroarenes p-dichlorobenzene and hexachlorobenzene. When optimized, the foregoing approach is significantly more effective than those of currently known transition metal carbene complexes. The most active catalysts were found to be the monocarbene complexes of palladium chloride and iodide, both of which feature highly branched aromatic substituents (11a,b).en_US
dc.description.sponsorshipUkrainian Academy of Sciences 140en_US
dc.description.sponsorshipRobert A. Welch Foundation F-0003en_US
dc.language.isoEnglishen_US
dc.relation.ispartofen_US
dc.rightsAdministrative deposit of works to Texas ScholarWorks: This works author(s) is or was a University faculty member, student or staff member; this article is already available through open access or the publisher allows a PDF version of the article to be freely posted online. The library makes the deposit as a matter of fair use (for scholarly, educational, and research purposes), and to preserve the work and further secure public access to the works of the University.en_US
dc.subjectdehalogenationen_US
dc.subjectactivationen_US
dc.subjectreductionen_US
dc.subjecthalidesen_US
dc.subjectnickelen_US
dc.subjectchemistry, inorganic & nuclearen_US
dc.titleExceptionally Efficient Catalytic Hydrodechlorination of Persistent Organic Pollutants: Application of New Sterically Shielded Palladium Carbene Complexesen_US
dc.typeArticleen_US
dc.description.departmentChemistryen_US
dc.rights.restrictionOpenen_US
dc.identifier.doi10.1039/c4dt02908aen_US
dc.contributor.utaustinauthorEvans, Daniel A.en_US
dc.contributor.utaustinauthorCowley, Alan H.en_US
dc.relation.ispartofserialDalton Transactionsen_US


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