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Organic geochemistry of an oil and gas seep in northern Gulf of Mexico sediments
(1984)
During an extensive geochemical and geophysical survey of the outer slope of the northwestern Gulf of Mexico nine piston cores were recovered which had visible liquid organic deposits. In three of the cores deposits were ...
Expanding the coordination chemistry of bismuth : synthesis and characterization of heavy pnictogen ligated 3d transition metal complexes
(2022-07-30)
The coordination chemistry of the very heavy pnictogens, bismuth in particular, have been historically underdeveloped compared to the chemistry of their lighter congeners. Unlike nitrogen and phosphorous, among the most ...
Synthesis and application of electrochemically active oligonucleotides
(2017-05)
Modified oligonucleotides with redox-active functional groups could emerge as attractive tools for sensor development. In principle, changes in oligonucleotide hybridization or conformation may be read out as a change in ...
Advancement of photodissociation mass spectrometry methods for the analysis of protein post-translational modifications
(2016-05)
Post-translational modifications (PTMs) are important for regulating protein structure and function. Despite significant progress for PTM analysis using liquid chromatography tandem mass spectrometry (LC-MS/MS), opportunities ...
Development of the "NoSlip": a simple yet sophisticated paper analytical device for detection of proteins
(2016-05)
The two most successful commercial sensors in self-diagnostics are the pregnancy test and the blood glucose meter. Our opinion is that too much time has gone by without successful commercialization of more consumer operated ...
Transition metal catalyzed C-C bond formation : advances in carbonyl addition
(2017-08)
Transition metal catalyzed transfer hydrogenative methods for carbon-carbon bond construction are attractive alternatives to tradition carbonyl addition protocols. By generating carbonyl and organometallic species in-situ, ...
Development of ultraviolet photodissociation mass spectrometry strategies for the characterization of biomolecular structure
(2022-05-09)
Ultraviolet photodissociation (UVPD) is an alternative high-energy ion activation technique implemented to produce information rich tandem mass spectra. Dissociation of biomolecules by UVPD results in structure dependent ...
Syntheses of calix[4]pyrrole–based receptors and applications for therapeutics and environmental remediation
(2022-11-30)
Significant efforts have been made to develop synthetic receptors with high selectivity and affinity for specific anions or ion pairs. Calix[4]pyrroles, conformationally flexible tetrapyrrolic macrocycles defined by sp³ ...
Chemical sequencing of sequence-defined polymers by controlled degradation : studies and applications
(2021-11-29)
Sequence-defined polymers are a promising platform of discovery for the fields of biomimetics, self-assembly, catalysis, and information storage. The power of these polymers lies in their primary structure, which can beget ...