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Perovskite oxide electrode materials for energy conversion and storage
(2016-09-16)
The development of renewable energy conversion and storage technologies has become a leading focus of the fields of Materials Chemistry and Electrochemistry, with the ultimate goal of converting energy generated by renewable ...
(Rh(CO)₂Cl)₂-catalyzed allylic substitution reactions and domino sequences and application of the Pauson-Khand reaction to the synthesis of azabicyclic structures: total synthesis of (-)-alstonerine
(2007)
Examination of the scope of the [Rh(CO)₂Cl]₂-catalyzed allylic substitution reaction as well as the development of a domino [Rh(CO)₂Cl]₂-catalyzed allylic alkylation/Pauson Khand reaction is described. A number of experiments ...
Synthesis of organic biaryl and aryl silyl ether linkers for surface functionalization of silicon semiconductors
(2017-02-07)
Functional organic materials for use in inorganic semiconductor applications is of high scientific interest due to the need for flexible, conductive materials that can be utilized in solar energy applications. Herein is ...
Transition metal catalyzed carbonyl additions under the conditions of transfer hydrogenation
(2011-05)
The efficient construction of complex organic molecules mandates that an assortment of methods for forming C-C bonds be available to the practicing synthetic chemist. The addition of carbon based nucleophiles to carbonyl ...
Annulated bis(imidazolium) salts: synthesis, characterization, and applications
(2007-12)
The design, synthesis, characterization, and applications of annulated bis(imidazolium) salts are described. New synthetic methodologies have been developed that allow access to a broad structural range of bis(imidazolium) ...
Synthesis & characterization of new amethyrin-based expanded porphyrin metal complexes
(2017-09-27)
New expanded porphyrins are of interest in terms of understanding the electrochemical features of oligopyrroles and the determinants of aromaticity. They can also act as ligands to stabilize metal complexes whose structures ...
Development of new methodologies for the synthesis of expanded porphyrins and aspects of the conformational behavior of some previously unknown oligopyrrolic systems
(2002)
In spite of the considerable number of expanded porphyrin systems that
are now known, methods for synthesizing these compounds remain quite limited.
Aspects of this dissertation address this problem. For instance, in ...
Synthetic studies on the pluramycin family of antitumor antibiotics : the total synthesis of isokidamycin
(2010-12)
A total synthesis of the complex C-aryl glycoside isokidamycin was achieved during an effort to construct the natural product kidamycin, a member of the pluramycin family of antitumor antibiotics. The angolosamine ...
The behavior of proteins at solid-liquid interfaces
(2014-05)
The behavior of a protein molecule at the solid-liquid interface is a worthy scientific problem for at least three reasons. The main driving force for studying this problem is a practical one, as many areas of bio-related ...
Methods development and measurements for understanding morphological effects on electronic and optical properties in solution processable photovoltaic materials
(2012-12)
The effects of morphology on electronic and optical properties in solution processable photovoltaic (PV) materials have been studied through two different approaches. One approach, scanning photocurrent (PC) and photoluminescence ...