Modeling of temperature effect on low salinity waterflooding

Abstract

Recent studies have shown that additional oil can be achieved by modifying the composition and/or salinity of the injection water. Low salinity waterflooding gains popularity due to its low cost, availability of water, and high displacement efficiency of light to medium gravity oil. Various mechanisms behind low salinity waterflooding have been proposed. However, the dominant underlying mechanism is still under debate due to the complex nature of the interaction between crude oil/brine/rock (COBR). Temperature has been reported to play a significant role in the process of low salinity waterflooding, particularly in carbonates. Temperature may affect geochemical reactions between rock surface, crude oil, and water and consequently alter the rock wettability. Investigating the temperature effect not only helps identify optimum condition to achieve additional oil recovery but also contributes to understanding the mechanisms behind low salinity waterflooding. In order to investigate the temperature effect on low salinity waterflooding, we implemented an energy module in the UTCOMP-IPhreeqc simulator. Hereafter, we refer to the improved simulator as “non-isothermal UTCOMP-IPhreeqc.” UTCOMP-IPhreeqc is capable of modeling non-isothermal, multi-dimensional, and multi-phase transport process with geochemical calculations between water, minerals, gases, ion exchangers, kinetics, and surface complexes. Non-isothermal UTCOMP-IPhreeqc was then applied to study the temperature effect on low salinity coreflood experiments of sandstone and carbonate rocks based on the laboratory work of Kozaki (2012) and Chandrasekhar (2013), respectively. Our simulation results revealed that for the sandstone case, changing the temperature from 30 to 120 ºC has insignificant effect on the oil recovery. We believe the reason is due to the fact that for this specific case the total ionic strength and the viscosity ratio (water viscosity over oil viscosity) did not change with increasing temperature. Noteworthy, double-layer expansion is assumed to be the underlying mechanism for low salinity waterflooding in sandstones in non-isothermal UTCOMP-IPhreeqc. On the other hand, the total ionic strength is the main controlling parameter for the double-layer expansion. For the carbonate case, with increasing temperature from 120 to 150 ºC, oil recovery increased for both formation brine and low salinity water injection. The reason: while the viscosity ratio remained constant, calcite dissolution increases as the temperature increases. The calcite dissolution is assumed to be the underlying mechanism for low salinity water in carbonates in non-isothermal UTCOMP-IPhreeqc. Hence, as more calcite dissolves the wettability of the rock changes towards more water-wet. As a result, oil recovery improves.