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dc.contributor.advisorChristopher W. Bielawskien
dc.creatorChao, Steven Tai-hsiangen
dc.date.accessioned2011-08-31T21:54:06Zen
dc.date.available2011-08-31T21:54:06Zen
dc.date.issued2008en
dc.identifier.urihttp://hdl.handle.net/2152/13359en
dc.description.abstractThe research presented in this thesis is centered on the design and synthesis of molecules which are derived from benzimidazoles and their applications. The first chapter provides an introduction to benzimidazoles and N-heterocyclic carbenes, a unique class of molecules derived from benzimidazoles. The second chapter describes the use of benzobis(imidazolium) salts in the design and development of a new class of fluorescent materials demonstrated to be robust with strong photoluminescent properties as well as tunable electronic and physical characteristics. These materials have potential application as fluorophores, sensory materials, and models for photophysical studies. The final chapter describes the development of a mechanically-activated catalyst system with applications to stress-responsive and self-healing materials.en
dc.language.isoengen
dc.subjectCollege of Natural Sciencesen
dc.subjectbenzimidazolesen
dc.subjectN-heterocyclic carbenesen
dc.subjectbenzobis(imidazolium) saltsen
dc.subjectfluorophoresen
dc.subjectmechanically-activated catalyst systemen
dc.subjectsynthesisen
dc.subjectsensory materialsen
dc.titleDesigner benzimidazoles: Synthesis, characterization, and applicationsen
dc.typeThesisen
dc.description.departmentChemistryen


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