Browsing by Subject "Metathesis (Chemistry)"
Now showing items 1-3 of 3
Applications of ring-closing metathesis in construction of alkaloid natural products : synthetic studies on the immunosuppressant FR901483 and lundurines A-C (2008-05)Ring-closing metathesis (RCM) has proven to be a valuable tool for constructing alkaloid-like, poly-cyclic compounds. The syntheses of alkaloid structures we were interested in developing, could utilize RCM to construct a ...
I. The synthesis of homoallylic amines via a 1,2-metalate rearrangement; II. The synthesis of bridged azabicyclic structures via ring-closing olefin metathesis (2003-05)A convergent, stereoselective route to homoallylic sulfonamides has been described. Homoallylic sulfonamides with di- and trisubstituted double bonds were prepared in good yields and with excellent control of alkene ...