Browsing by Subject "metal-organic frameworks"

Now showing 1 - 4 of 4

Construction of 1-D 4F and 3D-4F Coordination Polymers with Flexible Schiff Base Ligands
(2011-07) Yang, Xiaoping; Lam, Daniel; Chan, Christopher; Stanley, Julie M.; Jones, Richard A.; Holliday, Bradley J.; Wong, Wai-Kwok; Yang, Xiaoping; Lam, Daniel; Chan, Christopher; Stanley, Julie M.; Jones, Richard A.; Holliday, Bradley J.
Three new lanthanide 1-D coordination polymers ({[Ln(2)(H2L)(OAc)(6)]center dot EtOH center dot 2H(2)O}(n) (Ln = Eu (1), Er (2)) and {YbNiLCl(OAc)(2)(H2O)}(n) (3)) and a heterobinuclear complex [YbNiLCl3(H2O)(3)] (4) are reported which are formed from salen type Schiff-base ligands H2L (H2L = N,N'-bis(3-methoxysalicylidene) butane-1,4-diamine). The polymeric structures are formed by bridging H2L units in the case of 1 and 2, and by acetate groups in 3. The structures of 1-4 were determined by single crystal X-ray crystallographic studies and their luminescence properties in MeCN solution were determined.
Dynamic 2D Manganese(II) Isonicotinate Framework with Reversible Crystal-To-Amorphous Transformation and Selective Guest Adsorption
(2014-04) Matoga, Dariusz; Gil, Barbara; Nitek, Wojciech; Todd, Alexander D.; Bielawski, Christopher W.; Todd, Alexander D.; Bielawski, Christopher W.
A 2D layered microporous isonicotinate-supported manganese(II) metal-organic framework was found to exhibit a reversible crystalto-amorphous transformation upon the removal and uptake of certain guest molecules. Unsaturated metal centers, generated in the dynamic framework upon activation, were found to facilitate the selective adsorption of CO2 versus N-2.
Syntheses, Structures, and Photoluminescence of 1-D Lanthanide Coordination Polymers
(2009-10) Yang, Xiaoping; Jones, Richard A.; Rivers, Joseph H.; Wong, Wai-Kwok; Yang, Xiaoping; Jones, Richard A.; Rivers, Joseph H.
Five new lanthanide 1-D coordination polymers are reported which are formed from flexible salen type Schiff-base ligands H(2)L and H(2)L' (H(2)L = N, N(1)-ethylene bis(salicylideneimine); H(2)L' = N,N(1)-bis(3-methoxysalicylidene) ethylene-1,2-diamine). The polymeric structures are formed by bridging neutral H(2)L units in the case of {[Ln(2)L(2)(CF(3)SO(3))(H(2)L)(4)(MeOH)]center dot CF(3)SO(3)}(n) (Ln = Eu (1), Nd (2) and Er (3)), and by acetate (OAc(-)) groups in [Yb(2)(L)(2)(OAc)(2)(MeOH)(2)](n) (4) and {[Tb(3)(L')(2)(OAc)(5)]center dot Et(2)O center dot(MeOH)(0.5)}(n) (5). The structures of 1-5 were determined by single crystal X-ray crystallographic studies and the luminescence properties of 1 and 5 in MeOH solution were determined.
Synthesis and Crystal Structures of Lanthanide 4-Benzyloxy Benzoates: Influence of Electron-Withdrawing and Electron-Donating Groups On Luminescent Properties
(2009-11) Sivakumar, Sarika; Reddy, M. L. P.; Cowley, Alan H.; Vasudevan, Kalyan V.; Cowley, Alan H.; Vasudevan, Kalyan V.
Three new 4-benzyloxy benzoic acid derivatives [4-benzyloxy benzoic acid = HL1; 3-methoxy-4-benzyloxy benzoic acid = HL2; 3-nitro-4-benzyloxy benzoic acid = HL3] have been employed as ligands for the support of six lanthanide coordination compounds [Tb3+ = 1-3; Eu3+ = 4-6] with the aim of testing the influence of electron releasing (-OMe) or electron withdrawing (-NO2) substituents on the photophysical properties. The new complexes have been characterized by a variety of spectroscopic techniques and two of the Tb3+ complexes [1 and 2] have been structurally authenticated by single-crystal X-ray diffraction. Compounds 1 and 2 crystallize in the monoclinic space group P2(1)/n and their molecular structures consist of homodinuclear species that are bridged by two oxygen atoms from two benzoate ligands. In the case of 1, the carboxylate ligands coordinate to the central Tb3+ ion in bidentate chelating and bidentate bridging modes. By contrast, three different coordination modes (bidentate chelating, bidentate bridging and monodentate) are observed in the case of compound 2. Examination of the packing diagrams for 1 and 2 revealed the presence of a one-dimensional molecular array that is held together by intermolecular hydrogen-bonding interactions. The incorporation of an electron-releasing substituent on position 3 of 4-benzyloxy benzoic acid increases the electron density of the ligand and consequently improves the photoluminescence of the Tb3+ complexes. On the other hand, the presence of an electron-withdrawing group at this position dramatically decreases the overall sensitization efficiency of the Tb3+-centered luminescence due to dissipation of the excitation energy by means of a pi*-n transition of the NO2 substituent along with the participation of the ILCT bands. The weaker photoluminescence of the Eu3+ complexes is attributable to the poor match of the triplet energy levels of the 4-benzyloxy benzoic acid derivatives with that of the emitting level of the central metal ion.