Reducing environmental impacts of petroleum refining : a case study of industrial flaring

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Reducing environmental impacts of petroleum refining : a case study of industrial flaring

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dc.contributor.advisor Allen, David T.
dc.creator Alfadhli, Fahad Mohammed
dc.date.accessioned 2012-10-04T19:54:12Z
dc.date.available 2012-10-04T19:54:12Z
dc.date.created 2012-08
dc.date.issued 2012-10-04
dc.date.submitted August 2012
dc.identifier.uri http://hdl.handle.net/2152/ETD-UT-2012-08-5962
dc.description.abstract Industrial flaring can have negative impacts on regional air quality and recent studies have shown that flares are often operated at low combustion efficiency, which exacerbates these air quality impacts. This thesis examines industrial flaring with the objectives of (1) assessing the air quality impacts of flares operating at a variety of conditions, (2) examining the extent to which improvements in flare operations could reduce emissions, (3) identifying opportunities for recycling flared gases in fuel gas networks, and (4) identifying opportunities for reducing the generation of flared gases, using the improved control of catalytic cracking operations as a case study. The work presented in this thesis demonstrates that flares operating at low combustion efficiency can increase localized ambient ozone concentrations by more than 15 ppb under some conditions. The impact of flares on air quality depends most strongly on combustion efficiency, the flow rates to the flares and the chemical composition (photochemical reactivity) of the emissions. Products of incomplete combustion and nitrogen oxides emissions from flaring generally had a smaller impact on air quality than unburned flare gases. The combustion efficiency at which a flare can operate can be constrained by the flare’s design. In a case study of an air-assisted flare, it was demonstrated that choices in blower configurations could lead to emissions that were orders of magnitude greater or less than those predicted using an assumed combustion efficiency of 98%. Designing flares with air-assist rates that can be finely tuned can significantly reduce emissions. Similarly, flaring can be reduced by integrating sources of waste gases into fuel gas networks. Analyses for a petroleum refinery indicated that this integration can often be accomplished with little net cost by expanding boiler capacities. Finally, flared gases can be reduced at their source. A case study of a fluid catalytic cracking indicated that using better temperature control could significantly minimize flared gases.
dc.format.mimetype application/pdf
dc.language.iso eng
dc.subject Low combustion efficiency
dc.subject Industrial flares
dc.subject Destruction removal efficiency
dc.title Reducing environmental impacts of petroleum refining : a case study of industrial flaring
dc.date.updated 2012-10-04T19:54:28Z
dc.identifier.slug 2152/ETD-UT-2012-08-5962
dc.contributor.committeeMember Edgar, Thomas F.
dc.contributor.committeeMember McDonald-Buller, Elena
dc.contributor.committeeMember Baldea, Michael
dc.contributor.committeeMember Torres, Vincent M.
dc.description.department Chemical Engineering
dc.type.genre thesis
dc.type.material text
thesis.degree.department Chemical Engineering
thesis.degree.discipline Chemical Engineering
thesis.degree.grantor University of Texas at Austin
thesis.degree.level Doctoral
thesis.degree.name Doctor of Philosophy

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