Vapor transport techniques for growing macroscopically uniform zinc oxide nanowires

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Vapor transport techniques for growing macroscopically uniform zinc oxide nanowires

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Title: Vapor transport techniques for growing macroscopically uniform zinc oxide nanowires
Author: Baker, Chad Allan
Abstract: ZnO nanowires were grown using carbothermal reduction and convective vapor phase transport in a tube furnace. Si <100> substrates that were 20 mm x 76.2 mm were sputter coated with 2 nm to 50 nm gold which formed nanoparticles on the order of 50 nm in diameter through a process of Ostwald ripening upon being heated. Growth temperatures were varied from 800ºC to 1000ºC, flow rates were varied from 24 sccm to 3300 sccm, and growth durations were varied from 8 minutes to 5 hours. Vapor phase Zn, CO, and CO2, produced by carbothermal reduction and suspended in an Ar atmosphere, were flowed over the Si substrates. The Au nanoparticles formed an eutectic alloy with Zn, causing them to become liquid nanodroplets which catalyzed vapor-liquid-solid nanowire growth. The nanowires were also synthesized by self-catalyzing vapor-solid growth in some cases. Using the tube furnace never resulted in more than 50% of the substrate being covered by nanowires. It was found that a bench-top furnace could achieve nearly 100% nanowire coverage by placing the 20 mm x 76.2 mm sample face down in a quartz boat less than 2 mm above the source powder. This was because minimizing the distance between the sample and the source powder was critical to achieve macroscopically uniform growth consistently.
Department: Mechanical Engineering
Subject: nanowires nano-wires catalyst catalytic vapor-liquid-solid vapor liquid solid vapor-solid vapor solid vapor-solid-solid vapor solid solid carbothermal ZnO zinc oxide nanocombs nano rugosity vapor transport vapor phase transport
URI: http://hdl.handle.net/2152/ETD-UT-2009-08-363
Date: 2009-08

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